First Challenge Benchmark Data
Problem 1a |
Vapor-Liquid Equilibria for Dimethyl Ether(1) + Propylene(2) | |||
|---|---|---|---|---|
| Problem Conditions | (1) Px data at 253.15 K | (2) Px data at 293.15 K | ||
| x1=0.0, 0.2, 0.4, 0.6, 0.8, 1.0 | x1=0.5 (mole fractions) | |||
| Recommended Experimental Values: | x1 | (kPa) | x1 | (kPa) |
| 0.0 | 307.2 ± 0.5 | 0.5 | 794.4 ± 1.2 | |
| 0.2 | 277.3 ± 0.5 | |||
| 0.4 | 245.7 ± 0.5 | |||
| 0.6 | 210.8 ± 0.5 | |||
| 0.8 | 170.9 ± 0.5 | |||
| 1.0 | 125.0 ± 0.5 | |||
Problem 1b |
Vapor-Liquid Equilibria for Nitroethane (1) + Propylene Glycol Monomethyl Ether (2) | |||
| Problem Conditions | (1) Azeotropic/Px data at 353.15 K | (2) Azeotropic/Px data at 313.15 K | ||
| x1=azeotrope, 0.2, 0.5 | x1=azeotrope, 0.2, 0.5 | |||
| Recommended Experimental Values: | x1 | (kPa) | x1 | (kPa) |
| 0.2 | 29.36 ± 0.06 | 0.2 | 4.92 ± 0.1 | |
| 0.5 | 33.54 ± 0.06 | 0.5 | 5.96 ± 0.1 | |
| Azeotrope | 0.765 ± 0.045 | 34.72 ± 0.05 | 0.825 ± 0.045 | 6.34 ± 0.1 |
Problem II(a) |
Water Density | |||
| Problem Conditions | 0.1 MPa, 293 K | 2.0 MPa, 423 K | ||
| Recommended Experimental Values: | 998.237 ± 0.001 kg·m-3 | 918.012 ± 0.009 kg·m-3 | ||
Problem II(b) |
Cyclohexane Density | |||
| Problem Conditions | 0.1 MPa, 300 K | 20.0 MPa, 400 K | ||
| Recommended Experimental Values: | 772.13 ± 0.3 kg·m-3 | 702.9 ± 1.4 kg·m-3 | ||
Problem II(c) |
2-Propanol Density | |||
| Problem Conditions | 0.1 MPa, 298.15 K | 5 MPa, 400 K | ||
| Recommended Experimental Values: | 781.86 ± 0.70 kg·m-3 | 680.40 ± 2.72 kg·m-3 | ||
Problem II(d) |
Diethanol Amine Density | |||
| Problem Conditions | 0.1 MPa, 330 K | 5 MPa, 400 K | ||
| Recommended Experimental Values: | 1072.7 ± 0.3 kg·m-3 | 1025.2 ± 0.3 kg·m-3 | ||
Problem II(e) |
1,2,3-Trichloropropane Density | |||
| Problem Conditions | 0.1 MPa, 290 K | 1.5 MPa, 400 K | ||
| Recommended Experimental Values: | 1393.3 ± 0.3 kg·m-3 | 1245.9 ± 0.3 kg·m-3 | ||
Problem II(f) |
Triethylene Glycol Density | |||
| Problem Conditions | 0.1 MPa, 310 K | 2 MPa, 280 K | ||
| Recommended Experimental Values: | 1110.7 ± 0.3 kg·m-3 | 1135.0 ± 0.3 kg·m-3 | ||
Problem II(g) |
Pyridine Density | |||
| Problem Conditions | 0.1 MPa, 298 K | 10 MPa, 375 K | ||
| Recommended Experimental Values: | 978.2 ± 0.5 kg·m-3 | 909 ± 4 kg·m-3 | ||
Problem II(h) |
Aqueous Choline Chloride Density | |||
| Problem Conditions | 0.1 MPa, 298 K | 20% choline chloride | 1.0 MPa, 305 K | 10% choline chloride |
| Recommended Experimental Values: | 1020.52 ± 0.26 kg·m-3 | 1006.80 ± 0.60 kg·m-3 | ||
Problem II(i) |
Methanol + Water Density | |||
| Problem Conditions | 0.1 MPa, 325 K | 10 MPa, 400 K | ||
| Recommended Experimental Values: | 897.7 ± 1.1 kg·m-3 | 828.8 ± 1.5 kg·m-3 | ||
Problem III |
Viscosity of 2-Propanol + n-Nonane Mixtures | |||
| Problem Conditions | 0.1 MPa, 300 K | |||
| n-Nonane | 2-Propanol | x=0.5 2-Propanol | x=0.75 2-Propanol | |
| Recommended Experimental Values: | 0.650 ± 0.007 mPa×s | 1.986 ± 0.021 mPa×s | 0.756 ± 0.008 mPa×s |
1.040 ± 0.011 mPa×s |
